Issue 89, 2016

Ritter-type amination of C–H bonds at tertiary carbon centers using iodic acid as an oxidant

Abstract

The Ritter-type amination of a tertiary C–H bond using iodic acid (HIO3) as an oxidant, in the presence of N-hydroxyphthalimide (NHPI) is reported. This operationally simple method is conducted under metal-free conditions, is scalable, and efficiently provides valuable α-tertiary amine derivatives.

Graphical abstract: Ritter-type amination of C–H bonds at tertiary carbon centers using iodic acid as an oxidant

Supplementary files

Article information

Article type
Communication
Submitted
01 Sep 2016
Accepted
21 Sep 2016
First published
22 Sep 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 13082-13085

Ritter-type amination of C–H bonds at tertiary carbon centers using iodic acid as an oxidant

K. Kiyokawa, K. Takemoto and S. Minakata, Chem. Commun., 2016, 52, 13082 DOI: 10.1039/C6CC07164C

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