Issue 87, 2016
From the journal:

Chemical Communications

Alkaline-earth phosphonate MOFs with reversible hydration-dependent fluorescence†

Z. H. Fard,a   Y. Kalinovskyy,b   D. M. Spasyuk,c   B. A. Blight*b  and  G. K. H. Shimizu*a  

* Corresponding authors

a Department of Chemistry, University of Calgary, Calgary, Alberta T2N 1N4, Canada
E-mail: gshimizu@ucalgary.ca

b School of Physical Sciences, University of Kent, Canterbury, UK
E-mail: b.blight@kent.ac.uk

c Canadian Light Source, 44 Innovation Blvd., Saskatoon, Saskatchewan, Canada

Abstract

A new rigid tritopic phosphonic ligand, 2,4,6-tris(4-phosphonophenyl)pyridine (H6L), was synthesized and used to assemble isostructural barium (1) and strontium (2) phosphonate metal organic frameworks that exhibit fully reversible and selective water-dependent fluorescence red-shift at room temperature.

Graphical abstract: Alkaline-earth phosphonate MOFs with reversible hydration-dependent fluorescence

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Article information

DOI
https://doi.org/10.1039/C6CC06490F
Article type
Communication
Submitted
08 Aug 2016
Accepted
01 Oct 2016
First published
13 Oct 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 12865-12868

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Alkaline-earth phosphonate MOFs with reversible hydration-dependent fluorescence

Z. H. Fard, Y. Kalinovskyy, D. M. Spasyuk, B. A. Blight and G. K. H. Shimizu, Chem. Commun., 2016, 52, 12865 DOI: 10.1039/C6CC06490F

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