Issue 76, 2016
From the journal:

Chemical Communications

Enhancement of magnetic anisotropy in a Mn–Bi heterobimetallic complex†

Tyler J. Pearson,a   Majed S. Fataftaha  and  Danna E. Freedman*a  

* Corresponding authors

a Northwestern University, Department of Chemistry, 2145 Sheridan Rd., Evanston, Il, USA
E-mail: danna.freedman@northwestern.edu

Abstract

A novel Mn2+⋯Bi3+ heterobimetallic complex, featuring the closest Mn⋯Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn2+ to a heavy main group element, namely, bismuth.

Graphical abstract: Enhancement of magnetic anisotropy in a Mn–Bi heterobimetallic complex

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Article information

DOI
https://doi.org/10.1039/C6CC06369A
Article type
Communication
Submitted
01 Aug 2016
Accepted
25 Aug 2016
First published
01 Sep 2016

Chem. Commun., 2016,52, 11394-11397

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Enhancement of magnetic anisotropy in a Mn–Bi heterobimetallic complex

T. J. Pearson, M. S. Fataftah and D. E. Freedman, Chem. Commun., 2016, 52, 11394 DOI: 10.1039/C6CC06369A

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