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Issue 66, 2016
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Intermolecular iodofunctionalization of allenamides with indoles, pyrroles, and furans: synthesis of iodine-substituted Z-enamides

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Abstract

A new method was developed to synthesize iodine-substituted Z-enamides through N-iodosuccinimide-mediated intermolecular iodofunctionalization of allenamides with indoles, pyrroles, and furans. These reactions proceed rapidly and tolerate a broad scope of substrates. The conjugated sulfimide ion species probably acts as the key intermediate.

Graphical abstract: Intermolecular iodofunctionalization of allenamides with indoles, pyrroles, and furans: synthesis of iodine-substituted Z-enamides

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Publication details

The article was received on 16 Jun 2016, accepted on 19 Jul 2016 and first published on 20 Jul 2016


Article type: Communication
DOI: 10.1039/C6CC05046H
Citation: Chem. Commun., 2016,52, 10167-10170
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    Intermolecular iodofunctionalization of allenamides with indoles, pyrroles, and furans: synthesis of iodine-substituted Z-enamides

    H. Li, X. Li, Z. Zhao, T. Ma, C. Sun and B. Yang, Chem. Commun., 2016, 52, 10167
    DOI: 10.1039/C6CC05046H

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