Issue 50, 2016

Quinonediimines as redox-active organocatalysts for oxidative coupling of aryl- and alkenylmagnesium compounds under molecular oxygen

Abstract

It is revealed that N,N′-diphenyl-p-benzoquinonediimine works as a redox-active organocatalyst for the oxidative homo-coupling of aryl- and alkenylmagnesium compounds under molecular oxygen. The catalytic cycle was formally monitored by 1H NMR experiments.

Graphical abstract: Quinonediimines as redox-active organocatalysts for oxidative coupling of aryl- and alkenylmagnesium compounds under molecular oxygen

Supplementary files

Article information

Article type
Communication
Submitted
12 Apr 2016
Accepted
26 Apr 2016
First published
12 May 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 7790-7793

Quinonediimines as redox-active organocatalysts for oxidative coupling of aryl- and alkenylmagnesium compounds under molecular oxygen

T. Amaya, R. Suzuki and T. Hirao, Chem. Commun., 2016, 52, 7790 DOI: 10.1039/C6CC03053J

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