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Issue 14, 2016
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Cuprophilic interactions in highly luminescent dicopper(I)–NHC–picolyl complexes – fast phosphorescence or TADF?

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Abstract

This case study on a series of monomeric, dimeric and polymeric CuI chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T1 ↔ S1 and T1 → S0, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T1 emitters.

Graphical abstract: Cuprophilic interactions in highly luminescent dicopper(i)–NHC–picolyl complexes – fast phosphorescence or TADF?

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Publication details

The article was received on 22 Nov 2015, accepted on 18 Dec 2015 and first published on 04 Jan 2016


Article type: Communication
DOI: 10.1039/C5CC09659F
Citation: Chem. Commun., 2016,52, 2932-2935
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    Cuprophilic interactions in highly luminescent dicopper(I)–NHC–picolyl complexes – fast phosphorescence or TADF?

    J. Nitsch, F. Lacemon, A. Lorbach, A. Eichhorn, F. Cisnetti and A. Steffen, Chem. Commun., 2016, 52, 2932
    DOI: 10.1039/C5CC09659F

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