Issue 14, 2016
From the journal:

Chemical Communications

Pd-on-Si catalysts prepared via galvanic displacement for the selective hydrogenation of para-chloronitrobenzene†

Qian Wei,a   Yu-Sheng Shi,a   Ke-Qiang Sun*a  and  Bo-Qing Xu*a  

* Corresponding authors

a Innovative Catalysis Program, Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: kqsun@mail.tsinghua.edu.cn, bqxu@mail.tsinghua.edu.cn

Abstract

The direct redox reaction (galvanic displacement) between Pd2+ and substrate Si was used to deposit Pd on Si, and the Pd–Si catalysts enabled a chemoselective hydrogenation of para-chloronitrobenzene with the selectivity for para-chloroaniline higher than 99.9% at complete conversion of para-chloronitrobenzene.

Graphical abstract: Pd-on-Si catalysts prepared via galvanic displacement for the selective hydrogenation of para-chloronitrobenzene

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Article information

DOI
https://doi.org/10.1039/C5CC07474F
Article type
Communication
Submitted
06 Sep 2015
Accepted
13 Jan 2016
First published
13 Jan 2016

Chem. Commun., 2016,52, 3026-3029

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Pd-on-Si catalysts prepared via galvanic displacement for the selective hydrogenation of para-chloronitrobenzene

Q. Wei, Y. Shi, K. Sun and B. Xu, Chem. Commun., 2016, 52, 3026 DOI: 10.1039/C5CC07474F

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