Room-temperature selective oxidation of 2-naphthol to BINOL using a Au/SrTiO3–H2O2 catalytic system

Shin-ichi Naya; Yuta Hiramoto; Miwako Teranishi; Hiroaki Tada

doi:10.1039/C5CC06438D

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Room-temperature selective oxidation of 2-naphthol to BINOL using a Au/SrTiO₃–H₂O₂ catalytic system†

Shin-ichi Naya,^a Yuta Hiramoto,^b Miwako Teranishi^a and Hiroaki Tada*^ab

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* Corresponding authors

^a Environmental Research Laboratory, Kinki University, 3-4-1, Kowakae, Higashi-Osaka, Osaka 577-8502, Japan
Fax: +81-6-6721-2500
Tel: +81-6-6721-2332

^b Department of Applied Chemistry, School of Science and Engineering, Kinki University, 3-4-1, Kowakae, Higashi-Osaka, Osaka 577-8502, Japan
E-mail: h-tada@apch.kindai.ac.jp
Fax: +81-6-6727-4301
Tel: +81-6-6721-2332

Abstract

Gold nanoparticle-loaded SrTiO₃ (Au/SrTiO₃) effectively catalyzes the selective C–C bond formation between 2-naphthol molecules to yield BINOL in the presence of H₂O₂, and the catalytic activity increases with decreasing Au particle size (d) in the range 2.6 ≤ d ≤ 8.9 nm.

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Article information

DOI: https://doi.org/10.1039/C5CC06438D
Article type: Communication
Submitted: 01 Aug 2015
Accepted: 06 Oct 2015
First published: 06 Oct 2015

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Chem. Commun., 2015,51, 17669-17671

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Room-temperature selective oxidation of 2-naphthol to BINOL using a Au/SrTiO₃–H₂O₂ catalytic system

S. Naya, Y. Hiramoto, M. Teranishi and H. Tada, Chem. Commun., 2015, 51, 17669 DOI: 10.1039/C5CC06438D

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