Issue 92, 2015
From the journal:

Chemical Communications

Photocatalytic CO2 reduction using visible light by metal-monocatecholato species in a metal–organic framework†

Yeob Lee,a   Sangjun Kim,b   Honghan Fei,a   Jeung Ku Kang*b  and  Seth M. Cohen*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA
E-mail: scohen@ucsd.edu

b Graduate School of EEWS, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, Republic of Korea

Abstract

Metal–organic frameworks (MOFs) with isolated metal-monocatecholato groups have been synthesized via postsynthetic exchange (PSE) for CO2 reduction photocatalyst under visible light irradiation in the presence of 1-benzyl-1,4-dihydronicotinamide and triethanolamine. The Cr-monocatecholato species are more efficient than the Ga-monocatecholato species.

Graphical abstract: Photocatalytic CO2 reduction using visible light by metal-monocatecholato species in a metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C5CC04506A
Article type
Communication
Submitted
02 Jun 2015
Accepted
24 Sep 2015
First published
24 Sep 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 16549-16552

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Photocatalytic CO2 reduction using visible light by metal-monocatecholato species in a metal–organic framework

Y. Lee, S. Kim, H. Fei, J. K. Kang and S. M. Cohen, Chem. Commun., 2015, 51, 16549 DOI: 10.1039/C5CC04506A

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