Issue 50, 2015

Cp*Rh(iii) and Cp*Ir(iii)-catalysed redox-neutral C–H arylation with quinone diazides: quick and facile synthesis of arylated phenols

Abstract

Cp*Rh(III)- and Cp*Ir(III)-catalysed direct C–H arylation with quinone diazides as efficient coupling partners is disclosed. This redox-neutral protocol offers a facile, operationally simple and environmentally benign access to arylated phenols. The reaction represents the first example of Cp*Ir(III)-catalysed C–H direct arylation reaction.

Graphical abstract: Cp*Rh(iii) and Cp*Ir(iii)-catalysed redox-neutral C–H arylation with quinone diazides: quick and facile synthesis of arylated phenols

Supplementary files

Article information

Article type
Communication
Submitted
17 Apr 2015
Accepted
14 May 2015
First published
14 May 2015

Chem. Commun., 2015,51, 10240-10243

Author version available

Cp*Rh(III) and Cp*Ir(III)-catalysed redox-neutral C–H arylation with quinone diazides: quick and facile synthesis of arylated phenols

S. Zhang, C. Jiang, J. Wu, X. Liu, Q. Li, Z. Huang, D. Li and H. Wang, Chem. Commun., 2015, 51, 10240 DOI: 10.1039/C5CC03187G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements