Issue 37, 2015

Solvent-dependent strong asymmetric amplification in the catalytic enantioselective Henry reaction using the trans-N,N′-bis-biphenyl-4-ylmethyl-cyclohexane-1,2-diamine-CuCl2 complex

Abstract

A strong asymmetric amplification was observed in the enantioselective Henry reaction catalyzed by the (R,R)-trans-N,N′-bis-biphenyl-4-ylmethyl-cyclohexane-1,2-diamine·CuCl2 complex in AcOEt, while no amplification occurred in MeOH.

Graphical abstract: Solvent-dependent strong asymmetric amplification in the catalytic enantioselective Henry reaction using the trans-N,N′-bis-biphenyl-4-ylmethyl-cyclohexane-1,2-diamine-CuCl2 complex

Supplementary files

Article information

Article type
Communication
Submitted
19 Mar 2015
Accepted
02 Apr 2015
First published
02 Apr 2015

Chem. Commun., 2015,51, 7907-7910

Solvent-dependent strong asymmetric amplification in the catalytic enantioselective Henry reaction using the trans-N,N′-bis-biphenyl-4-ylmethyl-cyclohexane-1,2-diamine-CuCl2 complex

K. Tanaka, T. Iwashita, E. Yoshida, T. Ishikawa, S. Otuka, Z. Urbanczyk-Lipkowska and H. Takahashi, Chem. Commun., 2015, 51, 7907 DOI: 10.1039/C5CC02302E

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