Issue 36, 2015
From the journal:

Chemical Communications

(E)-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases†

Chuan-Zhi Yao,‡a   Qiang-Qiang Li,‡a   Mei-Mei Wang,a   Xiao-Shan Ninga  and  Yan-Biao Kang*a  

* Corresponding authors

a Center of Advanced Nanocatalysis (CAN) and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
E-mail: ybkang@ustc.edu.cn

Abstract

An unprecedented base-promoted direct olefination of aryl alcohols with sulfones via a Julia-type reaction has been described. No extra reductants are needed for Julia reaction since alcohols work as double sources of aldehydes and the hydride. Generally high yields were given for both terminal and highly (E)-selective internal olefins.

Graphical abstract: (E)-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases

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Article information

DOI
https://doi.org/10.1039/C5CC01965F
Article type
Communication
Submitted
08 Mar 2015
Accepted
25 Mar 2015
First published
25 Mar 2015

Chem. Commun., 2015,51, 7729-7732

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(E)-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases

C. Yao, Q. Li, M. Wang, X. Ning and Y. Kang, Chem. Commun., 2015, 51, 7729 DOI: 10.1039/C5CC01965F

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