Anion-induced AgI self-assemblies with electron deficient aromatic ligands: anion–π-system interactions as a driving force for templated coordination networks

Damir A. Safin; Amélie Pialat; Alicea A. Leitch; Nikolay A. Tumanov; Ilia Korobkov; Yaroslav Filinchuk; Jaclyn L. Brusso; Muralee Murugesu

doi:10.1039/C5CC01597A

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Anion-induced Ag^I self-assemblies with electron deficient aromatic ligands: anion–π-system interactions as a driving force for templated coordination networks†

Damir A. Safin,^a Amélie Pialat,^a Alicea A. Leitch,^a Nikolay A. Tumanov,^b Ilia Korobkov,^a Yaroslav Filinchuk,^b Jaclyn L. Brusso^a and Muralee Murugesu*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Ottawa, 10 Marie Curie Private, Ottawa, ON, Canada K1N 6N5
E-mail: m.murugesu@uottawa.ca
Fax: +1 (613) 562 5170
Tel: +1 (613) 562 5800 ext. 2733

^b Institute of Condensed Matter and Nanosciences, Université catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-Neuve, Belgium

Abstract

Three novel 1D, 2D and 3D coordination polymers were successfully isolated using nitrogen based 3,6-bis(2′-pyrimidyl)-1,2,4,5-tetrazine (BPymTz) and 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) ligands with Ag^I ions. The formation of these supramolecular assemblies was templated through anion–π-system interactions.

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Article information

DOI: https://doi.org/10.1039/C5CC01597A
Article type: Communication
Submitted: 23 Feb 2015
Accepted: 24 Apr 2015
First published: 27 Apr 2015
This article is Open Access

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Chem. Commun., 2015,51, 9547-9550

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Anion-induced Ag^I self-assemblies with electron deficient aromatic ligands: anion–π-system interactions as a driving force for templated coordination networks

D. A. Safin, A. Pialat, A. A. Leitch, N. A. Tumanov, I. Korobkov, Y. Filinchuk, J. L. Brusso and M. Murugesu, Chem. Commun., 2015, 51, 9547 DOI: 10.1039/C5CC01597A

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