Issue 19, 2015
From the journal:

Chemical Communications

Selective synthesis of rhodium-based nanoframe catalysts by chemical etching of 3d metals†

Zhi-Ping Zhang,a   Wei Zhu,a   Chun-Hua Yana  and  Ya-Wen Zhang*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, PKU-HKU Joint Laboratory in Rare Earth Materials and Bioinorganic Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
E-mail: ywzhang@pku.edu.cn

Abstract

We demonstrate a general strategy for the highly selective synthesis of Rh-based multi-metallic nanoframes through preferential etching of 3d metals, including Cu and Ni. Compared with Rh–Cu nanooctahedrons/C, Rh–Cu nanooctahedral frames/C show greatly enhanced activity toward hydrazine decomposition at room temperature.

Graphical abstract: Selective synthesis of rhodium-based nanoframe catalysts by chemical etching of 3d metals

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Article information

DOI
https://doi.org/10.1039/C4CC10050F
Article type
Communication
Submitted
17 Dec 2014
Accepted
21 Jan 2015
First published
23 Jan 2015

Chem. Commun., 2015,51, 3997-4000

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Selective synthesis of rhodium-based nanoframe catalysts by chemical etching of 3d metals

Z. Zhang, W. Zhu, C. Yan and Y. Zhang, Chem. Commun., 2015, 51, 3997 DOI: 10.1039/C4CC10050F

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