Issue 13, 2015
From the journal:

Chemical Communications

A magnetically highly frustrated CuII27 coordination cluster containing a Cu18 folded-sheet motif†

Irina A. Kühne,a   George E. Kostakis, ORCID logo ‡b   Christopher E. Ansona  and  Annie K. Powell*ab  

* Corresponding authors

a Institut für Anorganische Chemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, D-76131 Karlsruhe, Germany
E-mail: annie.powell@kit.edu
Fax: +49 721 608 8142
Tel: +49 721 608 2135

b Institut für Nanotechnologie, Karlsruhe Institute of Technology (KIT), Postfach 3640, D-76021 Karlsruhe, Germany

Abstract

[CuII27(μ4-O)2(OH)13(OMe)7(vanox)10(NO3)8(OH2)2(MeOH)7](NO3)2·2H2O·11MeOH (1) was synthesised from Cu(NO3)2·3H2O and o-vanillin-oxime. Structural analysis shows a molecule composed of a Cu18 “folded-sheet” motif linked to a Cu9 bridging unit. The cluster is highly frustrated and has an S = 1/2 spin ground state.

Graphical abstract: A magnetically highly frustrated CuII27 coordination cluster containing a Cu18 folded-sheet motif

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Article information

DOI
https://doi.org/10.1039/C4CC09469G
Article type
Communication
Submitted
26 Nov 2014
Accepted
02 Jan 2015
First published
02 Jan 2015

Chem. Commun., 2015,51, 2702-2705

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A magnetically highly frustrated CuII27 coordination cluster containing a Cu18 folded-sheet motif

I. A. Kühne, G. E. Kostakis, C. E. Anson and A. K. Powell, Chem. Commun., 2015, 51, 2702 DOI: 10.1039/C4CC09469G

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