Issue 14, 2015

High-yield production of highly conductive graphene via reversible covalent chemistry

Abstract

On the basis of the Diels–Alder reaction of graphite and tetracyanoethylene, graphite has been mechanically exfoliated into graphene adducts in a yield up to 38%. The graphene adduct can restore its conjugated structure via retro-Diels–Alder reaction under mild conditions, exhibiting a high conductivity of 1035 S m−1.

Graphical abstract: High-yield production of highly conductive graphene via reversible covalent chemistry

Supplementary files

Article information

Article type
Communication
Submitted
16 Nov 2014
Accepted
06 Jan 2015
First published
07 Jan 2015

Chem. Commun., 2015,51, 2806-2809

Author version available

High-yield production of highly conductive graphene via reversible covalent chemistry

Z. Ji, J. Chen, L. Huang and G. Shi, Chem. Commun., 2015, 51, 2806 DOI: 10.1039/C4CC09144B

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