Issue 7, 2015

Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes

Abstract

The thiocarbamoylation of internal alkynes to produce tetrasubstituted β-aminocarbonyl vinyl sulfides was demonstrated using a nickel catalyst. This reaction was successful with a wide variety of substituents, and gave the syn-adducts exclusively.

Graphical abstract: Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes

Supplementary files

Article information

Article type
Communication
Submitted
15 Nov 2014
Accepted
27 Nov 2014
First published
05 Dec 2014

Chem. Commun., 2015,51, 1285-1288

Author version available

Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes

T. Inami, T. Kurahashi and S. Matsubara, Chem. Commun., 2015, 51, 1285 DOI: 10.1039/C4CC09123J

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