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Issue 7, 2015
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Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes

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Abstract

The thiocarbamoylation of internal alkynes to produce tetrasubstituted β-aminocarbonyl vinyl sulfides was demonstrated using a nickel catalyst. This reaction was successful with a wide variety of substituents, and gave the syn-adducts exclusively.

Graphical abstract: Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes

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Publication details

The article was received on 15 Nov 2014, accepted on 27 Nov 2014 and first published on 05 Dec 2014


Article type: Communication
DOI: 10.1039/C4CC09123J
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Citation: Chem. Commun., 2015,51, 1285-1288
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    Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes

    T. Inami, T. Kurahashi and S. Matsubara, Chem. Commun., 2015, 51, 1285
    DOI: 10.1039/C4CC09123J

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