Issue 18, 2015
From the journal:

Chemical Communications

Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd–NHC complex†

Benjamin J. Groombridge,a   Stephen M. Goldup*b  and  Igor Larrosa*c  

* Corresponding authors

a School of Biological and Chemical Sciences, Queen Mary University of London, Mile End Road, London, UK

b Department of Chemistry, University of Southampton, Highfield, Southampton, Hampshire, UK
E-mail: s.goldup@soton.ac.uk

c School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: igor.larrosa@manchester.ac.uk

Abstract

We report the first example of a general, exhaustive Pd-mediated cross-coupling of polychloroarenes in the presence of a deficit of nucleophiles, mediated by the highly active PEPPSI-IPent catalyst. Our results indicate that this catalyst system may be applicable to the pseudo-living polymerisation of chloroarene monomers.

Graphical abstract: Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd–NHC complex

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Article information

DOI
https://doi.org/10.1039/C4CC08920K
Article type
Communication
Submitted
07 Nov 2014
Accepted
20 Jan 2015
First published
04 Feb 2015

Chem. Commun., 2015,51, 3832-3834

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Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd–NHC complex

B. J. Groombridge, S. M. Goldup and I. Larrosa, Chem. Commun., 2015, 51, 3832 DOI: 10.1039/C4CC08920K

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