Issue 3, 2015

Frustrated Lewis pair behavior of monomeric (boryl)iminomethanes accessed from isocyanide 1,1-hydroboration

Abstract

The activation of carbon dioxide, organonitriles, and terminal acetylenes by (boryl)iminomethanes derived from isocyanide 1,1-hydroboration is described. Also detailed is the generality of hydroboration of m-terphenylisocyanides with hydroboranes of differing Lewis acidities.

Graphical abstract: Frustrated Lewis pair behavior of monomeric (boryl)iminomethanes accessed from isocyanide 1,1-hydroboration

Supplementary files

Article information

Article type
Communication
Submitted
11 Oct 2014
Accepted
07 Nov 2014
First published
10 Nov 2014

Chem. Commun., 2015,51, 541-544

Author version available

Frustrated Lewis pair behavior of monomeric (boryl)iminomethanes accessed from isocyanide 1,1-hydroboration

B. R. Barnett, C. E. Moore, A. L. Rheingold and J. S. Figueroa, Chem. Commun., 2015, 51, 541 DOI: 10.1039/C4CC08037H

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