Issue 81, 2014
From the journal:

Chemical Communications

Electron-spin excitation by implanting hydrogen into metallofullerene: the synthesis and spectroscopic characterization of Sc4C2H@Ih-C80†

Yongqiang Feng,a   Taishan Wang,*a   Jingyi Wu,b   Zhuxia Zhang,a   Li Jiang,a   Hongbin Han*c  and  Chunru Wang*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: wangtais@iccas.ac.cn, crwang@iccas.ac.cn
Fax: +86-10-62652120
Tel: +86-10-62652120

b Laboratory of Nuclear Analysis Techniques, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, China

c Department of Radiology, Peking University Third Hospital, Beijing 100191, China
E-mail: hanhongbin@bjmu.edu.cn

Abstract

A hydrogen-containing endohedral metallofullerene, Sc4C2H@Ih-C80, was synthesized and its paramagnetism was measured by the low-temperature EPR spectrometry with a broad EPR signal. The electron-spin excitation by implanting the H-atom would be a new method for preparation of stable paramagnetic metallofullerenes.

Graphical abstract: Electron-spin excitation by implanting hydrogen into metallofullerene: the synthesis and spectroscopic characterization of Sc4C2H@Ih-C80

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Article information

DOI
https://doi.org/10.1039/C4CC05783J
Article type
Communication
Submitted
25 Jul 2014
Accepted
25 Aug 2014
First published
25 Aug 2014

Chem. Commun., 2014,50, 12166-12168

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Electron-spin excitation by implanting hydrogen into metallofullerene: the synthesis and spectroscopic characterization of Sc4C2H@Ih-C80

Y. Feng, T. Wang, J. Wu, Z. Zhang, L. Jiang, H. Han and C. Wang, Chem. Commun., 2014, 50, 12166 DOI: 10.1039/C4CC05783J

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