Issue 74, 2014
From the journal:

Chemical Communications

A Mn(iii)/TEMPO-co-mediated tandem azidation–1,2-carbon migration reaction of allylic silyl ethers†

Zhi-Min Chen,a   Zhen Zhang,a   Yong-Qiang Tu,*ac   Ming-Hui Xu,a   Fu-Min Zhang,a   Chen-Chen Lia  and  Shao-Hua Wang*ab  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, P. R. China

b School of Pharmacy, Lanzhou University, Lanzhou, P. R. China

c Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, P. R. China
E-mail: tuyq@lzu.edu.cn, wangshh@lzu.edu.cn

Abstract

A novel Mn(III)/TEMPO-co-mediated tandem azidation–1,2-carbon migration reaction of allylic silyl ethers with an unactivated C[double bond, length as m-dash]C bond has been explored, generating α-aryl–alkyl β-azido ketones with an α-quaternary stereocenter.

Graphical abstract: A Mn(iii)/TEMPO-co-mediated tandem azidation–1,2-carbon migration reaction of allylic silyl ethers

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Article information

DOI
https://doi.org/10.1039/C4CC04707A
Article type
Communication
Submitted
20 Jun 2014
Accepted
22 Jul 2014
First published
23 Jul 2014

Chem. Commun., 2014,50, 10805-10808

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A Mn(III)/TEMPO-co-mediated tandem azidation–1,2-carbon migration reaction of allylic silyl ethers

Z. Chen, Z. Zhang, Y. Tu, M. Xu, F. Zhang, C. Li and S. Wang, Chem. Commun., 2014, 50, 10805 DOI: 10.1039/C4CC04707A

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