Issue 73, 2014
From the journal:

Chemical Communications

Highly double selective nitration of nitrostilbenes over zeolite†

Jun-Hui Xu,a   Jian-Ping Wei,a   Zheng Hao,a   Qing-Guo Maa  and  Xin-Hua Peng*a  

* Corresponding authors

a School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
E-mail: xhpeng@mail.njust.edu.cn

Abstract

A feasible zeolite-assisted ortho C–H nitration of nitrostilbenes has been developed for the first time, which can be used in situ. It uses acetyl nitrate as a mild, easily handled and commercially available nitrating reagent, leading to the synthesis of polynitrostilbenes with double selectivities and in good yields.

Graphical abstract: Highly double selective nitration of nitrostilbenes over zeolite

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Article information

DOI
https://doi.org/10.1039/C4CC04688A
Article type
Communication
Submitted
20 Jun 2014
Accepted
14 Jul 2014
First published
21 Jul 2014

Chem. Commun., 2014,50, 10710-10713

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Highly double selective nitration of nitrostilbenes over zeolite

J. Xu, J. Wei, Z. Hao, Q. Ma and X. Peng, Chem. Commun., 2014, 50, 10710 DOI: 10.1039/C4CC04688A

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