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Issue 72, 2014
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A molecular “screw-clamp”: accelerating click reactions in miniemulsions

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Abstract

The interface as a “screw clamp”: the copper-free 1,3-dipolar azide–alkyne cycloaddition at the interface of nanodroplets in miniemulsions was studied in detail by NMR spectroscopic methods. The reaction at the oil–water interface proved to exhibit higher rate constants, increased molecular weights and high regioregularity compared to the reaction in solution.

Graphical abstract: A molecular “screw-clamp”: accelerating click reactions in miniemulsions

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Publication details

The article was received on 29 May 2014, accepted on 17 Jul 2014 and first published on 17 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC04119D
Citation: Chem. Commun., 2014,50, 10495-10498
  • Open access: Creative Commons BY license
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    A molecular “screw-clamp”: accelerating click reactions in miniemulsions

    E. M. Alexandrino, P. Buchold, M. Wagner, A. Fuchs, A. Kreyes, C. K. Weiss, K. Landfester and F. R. Wurm, Chem. Commun., 2014, 50, 10495
    DOI: 10.1039/C4CC04119D

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