Issue 62, 2014
From the journal:

Chemical Communications

A covalent polyoxomolybdate-based hybrid with remarkable electron reservoir properties†

Corentin Rinfray,a   Séverine Renaudineau,a   Guillaume Izzet*a  and  Anna Proust*a  

* Corresponding authors

a Institut Parisien de Chimie Moléculaire Sorbonne Universités, UPMC Univ Paris 06, CNRS UMR 8232, Université Pierre et Marie Curie, 4 place Jussieu, case courrier 42, 75252 Paris Cedex 05, France
E-mail: anna.proust@upmc.fr

Abstract

A new polyoxomolybdate-based hybrid platform TBA4[PMo11O39{Sn(p-C6H4I)}] is reported. The presence of a post-functionalisable iodo-aryl moiety allows the grafting of a ferrocenyl moiety onto the POM. The electrochemical characterisation shows the effect of molybdenum on the electron reservoir properties of POM-based hybrids, which are further enhanced upon the addition of an acid.

Graphical abstract: A covalent polyoxomolybdate-based hybrid with remarkable electron reservoir properties

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Article information

DOI
https://doi.org/10.1039/C4CC03779K
Article type
Communication
Submitted
17 May 2014
Accepted
13 Jun 2014
First published
13 Jun 2014

Chem. Commun., 2014,50, 8575-8577

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A covalent polyoxomolybdate-based hybrid with remarkable electron reservoir properties

C. Rinfray, S. Renaudineau, G. Izzet and A. Proust, Chem. Commun., 2014, 50, 8575 DOI: 10.1039/C4CC03779K

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