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Issue 75, 2014
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A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M–R to vanadate oxo

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Abstract

A new mechanism for generating C–O bonds from metal-hydrocarbyls involving homolytic, intermolecular migration of the hydrocarbyl group to a vanadium oxo is reported. Responsible for the C–O bond in phenol formed by the reaction of OVCl3 with HgPh2, it may provide air-regenerable metal oxos a role in aerobic alkane oxidations.

Graphical abstract: A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M–R to vanadate oxo

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Publication details

The article was received on 24 Apr 2014, accepted on 28 Jul 2014 and first published on 28 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC03067B
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 10994-10996
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    A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M–R to vanadate oxo

    M. Cheng, R. J. Nielsen and W. A. Goddard III, Chem. Commun., 2014, 50, 10994
    DOI: 10.1039/C4CC03067B

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