Issue 73, 2014
From the journal:

Chemical Communications

Nucleophilic conjugate 1,3-addition of phosphines to oligoynoates†

Jie-Cheng Deng,‡a   Chih-Wei Kuo‡a  and  Shih-Ching Chuang*a  

* Corresponding authors

a Department of Applied Chemistry, National Chiao Tung University, Hsinchu 30010, Taiwan, Republic of China
E-mail: jscchuang@faculty.nctu.edu.tw
Fax: +886-35723764
Tel: +886-35731858

Abstract

Herein we have elucidated unusual and unique nucleophilic conjugate 1,3-addition reactions of surveyed oligoynoates toward phosphines through spectroscopic and single crystal X-ray diffraction analyses of three-component reaction products of oligoynoates, phosphines and aldehydes.

Graphical abstract: Nucleophilic conjugate 1,3-addition of phosphines to oligoynoates

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Article information

DOI
https://doi.org/10.1039/C4CC02870H
Article type
Communication
Submitted
18 Apr 2014
Accepted
09 Jun 2014
First published
11 Jun 2014

Chem. Commun., 2014,50, 10580-10583

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Nucleophilic conjugate 1,3-addition of phosphines to oligoynoates

J. Deng, C. Kuo and S. Chuang, Chem. Commun., 2014, 50, 10580 DOI: 10.1039/C4CC02870H

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