Issue 98, 2014
From the journal:

Chemical Communications

Oscillatory carbonylation using alkyne-functionalised poly(ethylene glycol)†

Lynn Donlona  and  Katarina Novakovic*a  

* Corresponding authors

a Department of Chemical Engineering and Advanced Materials, Newcastle University, Merz Court, Newcastle, UK
E-mail: katarina.novakovic@ncl.ac.uk
Fax: +44 (0)191 208 5748
Tel: +44 (0)191 208 3683

Abstract

In this study palladium-catalysed oscillatory carbonylation has been achieved using mono alkyne-terminated poly(ethylene glycol) methyl ether substrates. Reproducible, synchronised oscillations in pH and solution turbidity have been recorded over several days. A reaction network accounting for the observed phenomena has been proposed.

Graphical abstract: Oscillatory carbonylation using alkyne-functionalised poly(ethylene glycol)

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Article information

DOI
https://doi.org/10.1039/C4CC01548G
Article type
Communication
Submitted
28 Feb 2014
Accepted
16 Jun 2014
First published
17 Jun 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 15506-15508

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Oscillatory carbonylation using alkyne-functionalised poly(ethylene glycol)

L. Donlon and K. Novakovic, Chem. Commun., 2014, 50, 15506 DOI: 10.1039/C4CC01548G

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