Issue 42, 2014
From the journal:

Chemical Communications

A preferable molecular crystal membrane for H2 gas separation†

Yuichi Takasakia  and  Satoshi Takamizawa*a  

* Corresponding authors

a Department of Nanosystem Science, Graduate School of Nanobioscience, Yokohama City University, 22-2 Seto, Kanazawa-ku, Yokohama, Kanagawa 236-0027, Japan
E-mail: staka@yokohama-cu.ac.jp
Fax: +81-045-787-2187
Tel: +81-045-787-2187

Abstract

A novel molecular crystal membrane [Cu(II)2(9-AC)4(pyz)]n (9-AC: 9-anthracenecarboxylate, pyz: pyrazine) shows high permselectivity for H2/CO (79.0), H2/CH4 (137), and H2/CO2 (12.1) due to the high rate of H2 permeation (3820 Barrer) while inhibiting the permeation of such a large gaseous particle even in its wider channel than the Lennard-Jones diameter of each gas.

Graphical abstract: A preferable molecular crystal membrane for H2 gas separation

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Article information

DOI
https://doi.org/10.1039/C4CC01494D
Article type
Communication
Submitted
27 Feb 2014
Accepted
04 Apr 2014
First published
04 Apr 2014

Chem. Commun., 2014,50, 5662-5664

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A preferable molecular crystal membrane for H2 gas separation

Y. Takasaki and S. Takamizawa, Chem. Commun., 2014, 50, 5662 DOI: 10.1039/C4CC01494D

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