Issue 43, 2014
From the journal:

Chemical Communications

The use of a rigid tritopic phosphonic ligand for the synthesis of a robust honeycomb-like layered zirconium phosphonate framework†

Marco Taddei,*a   Ferdinando Costantino,a   Riccardo Vivani,b   Stefano Sabatini,b   Sang-Ho Limc  and  Seth M. Cohen*c  

* Corresponding authors

a Dipartimento di Chimica, Biologia e Biotecnologie, University of Perugia, Via Elce di Sotto 8, Perugia, Italy
E-mail: marcotaddei@hotmail.com

b Dipartimento di Scienze Farmaceutiche, University of Perugia, Via del Liceo 1, Perugia, Italy

c Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, USA
E-mail: scohen@ucsd.edu

Abstract

1,3,5-Tris(4-phosphonophenyl)benzene was synthesized via a microwave heating assisted route and was subsequently used for the preparation of a new zirconium phosphonate with honeycomb-like structure displaying remarkable thermal stability and hydrolysis resistance.

Graphical abstract: The use of a rigid tritopic phosphonic ligand for the synthesis of a robust honeycomb-like layered zirconium phosphonate framework

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Article information

DOI
https://doi.org/10.1039/C4CC01253D
Article type
Communication
Submitted
17 Feb 2014
Accepted
03 Apr 2014
First published
03 Apr 2014

Chem. Commun., 2014,50, 5737-5740

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The use of a rigid tritopic phosphonic ligand for the synthesis of a robust honeycomb-like layered zirconium phosphonate framework

M. Taddei, F. Costantino, R. Vivani, S. Sabatini, S. Lim and S. M. Cohen, Chem. Commun., 2014, 50, 5737 DOI: 10.1039/C4CC01253D

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