Issue 34, 2014
From the journal:

Chemical Communications

Oxygen and methanol mediated irreversible coordination polymer structural transformation from a 3D Cu(i)-framework to a 1D Cu(ii)-chain†

Jing-Yuan Ge,a   Jian-Cheng Wang,a   Jun-Yan Cheng,a   Peng Wang,a   Jian-Ping Ma,a   Qi-Kui Liua  and  Yu-Bin Dong*a  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China
E-mail: yubindong@sdnu.edu.cn

Abstract

An interesting irreversible structural transformation visible to the naked-eye occurs when a 3D Cu(I)–polymeric complex Cu2L(NO3)2(DMF)0.4 (1) is suspended in CH3OH in air to produce a 1D-Cu(II) polymeric complex Cu(μ-OCH3)(L)(NO3) (2) (L = 1,2-bis[4-(pyrimidin-4-yl)phenoxy]ethane). The transformation mechanism from 1 to 2 was also investigated.

Graphical abstract: Oxygen and methanol mediated irreversible coordination polymer structural transformation from a 3D Cu(i)-framework to a 1D Cu(ii)-chain

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Article information

DOI
https://doi.org/10.1039/C4CC00857J
Article type
Communication
Submitted
31 Jan 2014
Accepted
04 Mar 2014
First published
05 Mar 2014

Chem. Commun., 2014,50, 4434-4437

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Oxygen and methanol mediated irreversible coordination polymer structural transformation from a 3D Cu(I)-framework to a 1D Cu(II)-chain

J. Ge, J. Wang, J. Cheng, P. Wang, J. Ma, Q. Liu and Y. Dong, Chem. Commun., 2014, 50, 4434 DOI: 10.1039/C4CC00857J

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