Issue 27, 2014

Coordination polymers of organic polymers synthesized via photopolymerization of single crystals: two-dimensional hydrogen bonding layers with amazing shock absorbing nature

Abstract

Crystalline coordination polymers of organic polymers (CPOPs) were synthesized via photopolymerization of Ag(I) coordination polymers of dienes which have a self-templating nature due to the formation of N–H⋯O hydrogen bonded layers. The shock absorbing nature of the H-bonded layer facilitated the SCSC [2+2] transformation upon irradiation to produce CPOPs.

Graphical abstract: Coordination polymers of organic polymers synthesized via photopolymerization of single crystals: two-dimensional hydrogen bonding layers with amazing shock absorbing nature

Supplementary files

Article information

Article type
Communication
Submitted
24 Jan 2014
Accepted
10 Feb 2014
First published
11 Feb 2014

Chem. Commun., 2014,50, 3568-3570

Author version available

Coordination polymers of organic polymers synthesized via photopolymerization of single crystals: two-dimensional hydrogen bonding layers with amazing shock absorbing nature

M. Garai and K. Biradha, Chem. Commun., 2014, 50, 3568 DOI: 10.1039/C4CC00625A

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