Issue 47, 2014
From the journal:

Chemical Communications

Tripodal molecules for the promotion of phosphoester hydrolysis†

Jennifer R. Hiscock,a   Mark R. Sambrook,b   Philippa B. Cranwell,a   Pat Watts,b   Jack C. Vincent,b   David J. Xuereb,a   Neil J. Wells,a   Robert Rajaa  and  Philip A. Gale*a  

* Corresponding authors

a Chemistry, University of Southampton, Southampton, UK SO17 1BJ
E-mail: philip.gale@soton.ac.uk
Fax: +44 (0)23 8059 6805
Tel: +44 (0)23 8059 3322

b Detection Department, Dstl Porton Down, Salisbury
E-mail: m.sambrook@dstl.gov.uk
Tel: +44 (0)1980613306

Abstract

A series of low molecular weight tripodal amide/histidine-containing compounds (1–2) have been synthesised and shown to increase the rate of bis-(p-nitrophenyl) phosphate (BNPP) and soman (GD) breakdown in buffered aqueous solution.

Graphical abstract: Tripodal molecules for the promotion of phosphoester hydrolysis

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Article information

DOI
https://doi.org/10.1039/C4CC00333K
Article type
Communication
Submitted
15 Jan 2014
Accepted
23 Apr 2014
First published
30 Apr 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 6217-6220

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Tripodal molecules for the promotion of phosphoester hydrolysis

J. R. Hiscock, M. R. Sambrook, P. B. Cranwell, P. Watts, J. C. Vincent, D. J. Xuereb, N. J. Wells, R. Raja and P. A. Gale, Chem. Commun., 2014, 50, 6217 DOI: 10.1039/C4CC00333K

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