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Issue 19, 2014
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Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes

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Abstract

The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, the first neutral stable Ni(II)-hydride, and an unusual Cu(II) complex displaying a seesaw geometry, have been isolated.

Graphical abstract: Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes

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Publication details

The article was received on 10 Dec 2013, accepted on 15 Jan 2014 and first published on 15 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC49385G
Citation: Chem. Commun., 2014,50, 2431-2433
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    Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes

    D. I. Bezuidenhout, G. Kleinhans, G. Guisado-Barrios, D. C. Liles, G. Ung and G. Bertrand, Chem. Commun., 2014, 50, 2431
    DOI: 10.1039/C3CC49385G

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