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Issue 17, 2014
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Palladium-catalyzed P(O)R2 directed C–H arylation to synthesize electron-rich polyaromatic monophosphorus ligands

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Abstract

Palladium-catalyzed arylation of (diisopropylphosphoryl)biphenyl skeleton derivatives by the P(O)R2 directed C–H functionalization was reported. The related products were obtained in high regioselectivity and good functional group tolerance was observed. This reaction provided a new and efficient pathway for the synthesis of polyaromatic monophosphorus ligands.

Graphical abstract: Palladium-catalyzed P(O)R2 directed C–H arylation to synthesize electron-rich polyaromatic monophosphorus ligands

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Publication details

The article was received on 27 Nov 2013, accepted on 19 Dec 2013 and first published on 23 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC49050E
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 2193-2195
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    Palladium-catalyzed P(O)R2 directed C–H arylation to synthesize electron-rich polyaromatic monophosphorus ligands

    R. Hu, H. Zhang, X. Zhang and S. Yang, Chem. Commun., 2014, 50, 2193
    DOI: 10.1039/C3CC49050E

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