Issue 18, 2014
From the journal:

Chemical Communications

Iron(iii)-mediated photocatalytic selective substitution of aryl bromine by chlorine with high chloride utilization efficiency†

Ying Wang,a   Lina Li,a   Hongwei Ji,a   Wanhong Ma,a   Chuncheng Chen*a  and  Jincai Zhaoa  

* Corresponding authors

a Key Laboratory of Photochemistry, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China
E-mail: ccchen@iccas.ac.cn
Fax: +86 10-82616495

Abstract

An iron(III)-mediated photocatalytic method for the conversion of aryl, heteroaryl and polycyclic aromatic bromides to the corresponding chlorides with high selectivity has been achieved successfully. The mild reaction conditions and high chloride utilization efficiency promise a bright future for chlorination reactions.

Graphical abstract: Iron(iii)-mediated photocatalytic selective substitution of aryl bromine by chlorine with high chloride utilization efficiency

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Article information

DOI
https://doi.org/10.1039/C3CC48246D
Article type
Communication
Submitted
28 Oct 2013
Accepted
31 Dec 2013
First published
03 Jan 2014

Chem. Commun., 2014,50, 2344-2346

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Iron(III)-mediated photocatalytic selective substitution of aryl bromine by chlorine with high chloride utilization efficiency

Y. Wang, L. Li, H. Ji, W. Ma, C. Chen and J. Zhao, Chem. Commun., 2014, 50, 2344 DOI: 10.1039/C3CC48246D

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