An unprecedented octanuclear copper core with C3i symmetry and a paramagnetic ground state

Dmytro S. Nesterov; Julia Jezierska; Oksana V. Nesterova; Armando J. L. Pombeiro; Andrew Ozarowski

doi:10.1039/C3CC48107G

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An unprecedented octanuclear copper core with C_3i symmetry and a paramagnetic ground state†

Dmytro S. Nesterov,^a Julia Jezierska,^b Oksana V. Nesterova,^a Armando J. L. Pombeiro*^a and Andrew Ozarowski*^c

Author affiliations

* Corresponding authors

^a Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, Lisbon, Portugal
E-mail: pombeiro@tecnico.ulisboa.pt
Fax: +351 218464455

^b Faculty of Chemistry, University of Wroclaw, 14 Joliot-Curie Str., Wroclaw, Poland

^c National High Magnetic Field Laboratory, Florida State University, 1800 E. Paul Dirac Drive, Tallahassee, Florida 32310, USA
E-mail: ozarowsk@magnet.fsu.edu
Fax: +1 850-644-1366

Abstract

A complex of copper, possessing an octanuclear structure of high symmetry, has been prepared by a spontaneous self-assembly reaction of Cu(BF₄)₂ with N-tert-butyldiethanolamine and reveals a paramagnetic ground state.

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Article information

DOI: https://doi.org/10.1039/C3CC48107G
Article type: Communication
Submitted: 22 Oct 2013
Accepted: 08 Jan 2014
First published: 23 Jan 2014

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Chem. Commun., 2014,50, 3431-3434

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An unprecedented octanuclear copper core with C_3i symmetry and a paramagnetic ground state

D. S. Nesterov, J. Jezierska, O. V. Nesterova, A. J. L. Pombeiro and A. Ozarowski, Chem. Commun., 2014, 50, 3431 DOI: 10.1039/C3CC48107G

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