Issue 5, 2014

Unusual preservation of polyhedral molecular building units in a metal–organic framework with evident desymmetrization in ligand design

Abstract

A new porous metal–organic framework (MOF) with three types of preserved polyhedral molecular building units, all of which have been observed in a series of isostructural MOFs constructed from highly symmetrical hexacarboxylic ligands, was formed even from a pre-designed related tetracarboxylic ligand with drastically reduced symmetry.

Graphical abstract: Unusual preservation of polyhedral molecular building units in a metal–organic framework with evident desymmetrization in ligand design

Supplementary files

Article information

Article type
Communication
Submitted
22 Oct 2013
Accepted
05 Nov 2013
First published
25 Nov 2013

Chem. Commun., 2014,50, 563-565

Unusual preservation of polyhedral molecular building units in a metal–organic framework with evident desymmetrization in ligand design

Y. Xie, H. Yang, Z. U. Wang, Y. Liu, H. Zhou and J. Li, Chem. Commun., 2014, 50, 563 DOI: 10.1039/C3CC48089E

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