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Issue 25, 2014
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Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand

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Abstract

The diastereoselective formation of a meso-dinuclear Ru(II) complex of a novel bis-bidentate ligand is reported along with its electrochemical and photophysical properties. The design of the ligand, with its parallel coordination vectors, induces a diastereoselectivity of 1 : 13 : 1 [ΛΛ : (ΛΔ or ΔΛ) : ΔΔ] for the dinuclear complex.

Graphical abstract: Enhanced stereoselectivity in a di-Ru(ii) complex of an achiral bis-bidentate ligand

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Publication details

The article was received on 13 Oct 2013, accepted on 22 Dec 2013 and first published on 24 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC47856D
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 3303-3305
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    Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand

    A. K. Pal, P. D. Ducharme and G. S. Hanan, Chem. Commun., 2014, 50, 3303
    DOI: 10.1039/C3CC47856D

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