Issue 4, 2014

Photoreactivity of polymorphs of a ladder polymer with criss-cross and parallel orientations of C[double bond, length as m-dash]C bonds

Abstract

Two polymorphic forms of a ladder coordination polymer [Zn2(μ-O2C-p-Tol)2(O2C-p-Tol)2(bpe)2] have parallel and criss-cross alignments of the C[double bond, length as m-dash]C bond pairs. Both polymorphs undergo 100% [2+2] cycloaddition reaction but the one with a parallel orientation of C[double bond, length as m-dash]C bonds (thermodynamic product) retains its single crystallinity after the reaction.

Graphical abstract: Photoreactivity of polymorphs of a ladder polymer with criss-cross and parallel orientations of C [[double bond, length as m-dash]] C bonds

Supplementary files

Article information

Article type
Communication
Submitted
11 Oct 2013
Accepted
31 Oct 2013
First published
01 Nov 2013

Chem. Commun., 2014,50, 451-453

Photoreactivity of polymorphs of a ladder polymer with criss-cross and parallel orientations of C[double bond, length as m-dash]C bonds

A. Chanthapally, W. T. Oh and J. J. Vittal, Chem. Commun., 2014, 50, 451 DOI: 10.1039/C3CC47816E

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