Issue 8, 2014

Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

Abstract

Fe2(CO)4(μ-dppf)(μ-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.

Graphical abstract: Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

Supplementary files

Article information

Article type
Communication
Submitted
23 Aug 2013
Accepted
27 Nov 2013
First published
29 Nov 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 945-947

Author version available

Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

S. Ghosh, G. Hogarth, N. Hollingsworth, K. B. Holt, S. E. Kabir and B. E. Sanchez, Chem. Commun., 2014, 50, 945 DOI: 10.1039/C3CC46456C

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