Issue 5, 2014
From the journal:

Chemical Communications

First synthesis and aggregation behaviour of periconjugated triazoliumfullerene†

Naohiko Ikuma,*a   Saori Inaba,a   Ken Kokuboa  and  Takumi Oshimaa  

* Corresponding authors

a Division of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: ikuma@chem.eng.osaka-u.ac.jp

Abstract

Triazoliumfullerene was first prepared by the [3+2] cycloaddition of in situ generated 1,3-diaza-2-azoniaallene with fullerene and was characterized by the dispersed positive charge over the fullerene sphere associated with periconjugation. This new type of amphiphilic fullerene tended to form vesicles and crystalline aggregates after the casting of THF or MeOH solutions.

Graphical abstract: First synthesis and aggregation behaviour of periconjugated triazoliumfullerene

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Article information

DOI
https://doi.org/10.1039/C3CC45783D
Article type
Communication
Submitted
29 Jul 2013
Accepted
20 Oct 2013
First published
22 Oct 2013
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2014,50, 581-583

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First synthesis and aggregation behaviour of periconjugated triazoliumfullerene

N. Ikuma, S. Inaba, K. Kokubo and T. Oshima, Chem. Commun., 2014, 50, 581 DOI: 10.1039/C3CC45783D

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