Issue 97, 2013
From the journal:

Chemical Communications

Reduction-free synthesis of stable acetylide cobalamins†

Mikołaj Chromiński,a   Agnieszka Lewalskaa  and  Dorota Gryko*a  

* Corresponding authors

a Institute of Organic Chemistry Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland
E-mail: dorota.gryko@icho.edu.pl
Fax: +48 22 632 66 81
Tel: +48 22 343 2051

Abstract

A straightforward, reduction-free method for the synthesis of organometallic cobalamins has been developed. Stable phenylacetylide derivatives were characterized by X-ray analysis, showing a pronounced influence of the electronic nature of substituents on their structure.

Graphical abstract: Reduction-free synthesis of stable acetylide cobalamins

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Article information

DOI
https://doi.org/10.1039/C3CC47210H
Article type
Communication
Submitted
20 Sep 2013
Accepted
09 Oct 2013
First published
14 Oct 2013

Chem. Commun., 2013,49, 11406-11408

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Reduction-free synthesis of stable acetylide cobalamins

M. Chromiński, A. Lewalska and D. Gryko, Chem. Commun., 2013, 49, 11406 DOI: 10.1039/C3CC47210H

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