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Issue 94, 2013
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Highly diastereo- and enantioselective [3+2] annulation of isatin-derived Morita–Baylis–Hillman carbonates with trifluoropyruvate catalyzed by tertiary amines

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Abstract

An enantioselective [3+2] annulation of Morita–Baylis–Hillman carbonates with trifluoropyruvate catalyzed by modified cinchona alkaloids was developed in good to excellent yields with excellent diastereo- and enantioselectivities.

Graphical abstract: Highly diastereo- and enantioselective [3+2] annulation of isatin-derived Morita–Baylis–Hillman carbonates with trifluoropyruvate catalyzed by tertiary amines

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Publication details

The article was received on 29 Aug 2013, accepted on 05 Oct 2013 and first published on 07 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC46490C
Citation: Chem. Commun., 2013,49, 11071-11073
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    Highly diastereo- and enantioselective [3+2] annulation of isatin-derived Morita–Baylis–Hillman carbonates with trifluoropyruvate catalyzed by tertiary amines

    N. Zhong, F. Wei, Q. Xuan, L. Liu, D. Wang and Y. Chen, Chem. Commun., 2013, 49, 11071
    DOI: 10.1039/C3CC46490C

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