Issue 87, 2013

Why compete when you can share? Competitive reactivity of germanium and phosphorus with selenium

Abstract

Addition of one equivalent of selenium to a germanium–phosphanide complex results in insertion of selenium into the Ge–P bond, not oxidation at germanium or phosphorus. Addition of excess selenium results in oxidation at phosphorus, although of germanium oxidation is still observed.

Graphical abstract: Why compete when you can share? Competitive reactivity of germanium and phosphorus with selenium

Supplementary files

Article information

Article type
Communication
Submitted
05 Aug 2013
Accepted
10 Sep 2013
First published
17 Sep 2013

Chem. Commun., 2013,49, 10278-10280

Why compete when you can share? Competitive reactivity of germanium and phosphorus with selenium

E. C. Y. Tam, L. M. Harris, E. S. Borren, J. D. Smith, M. Lein, M. P. Coles and J. R. Fulton, Chem. Commun., 2013, 49, 10278 DOI: 10.1039/C3CC45954C

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