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Issue 90, 2013
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Dual role of allylsamarium bromide as a Grignard reagent and a single electron transfer reagent in the one-pot synthesis of terminal olefins

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Abstract

The utility of allylsamarium bromide, both as a nucleophilic reagent and a single-electron transfer reagent, in the reaction of carbonyl compounds with allylsamarium bromide in the presence of diethyl phosphate is reported in this communication. From a synthetic point of view, a simple one-pot method for the preparation of terminal olefins is developed.

Graphical abstract: Dual role of allylsamarium bromide as a Grignard reagent and a single electron transfer reagent in the one-pot synthesis of terminal olefins

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Publication details

The article was received on 24 Jul 2013, accepted on 25 Sep 2013 and first published on 26 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC45611K
Citation: Chem. Commun., 2013,49, 10635-10637
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    Dual role of allylsamarium bromide as a Grignard reagent and a single electron transfer reagent in the one-pot synthesis of terminal olefins

    Y. Li, Y. Hu and S. Zhang, Chem. Commun., 2013, 49, 10635
    DOI: 10.1039/C3CC45611K

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