Issue 90, 2013

Dual role of allylsamarium bromide as a Grignard reagent and a single electron transfer reagent in the one-pot synthesis of terminal olefins

Abstract

The utility of allylsamarium bromide, both as a nucleophilic reagent and a single-electron transfer reagent, in the reaction of carbonyl compounds with allylsamarium bromide in the presence of diethyl phosphate is reported in this communication. From a synthetic point of view, a simple one-pot method for the preparation of terminal olefins is developed.

Graphical abstract: Dual role of allylsamarium bromide as a Grignard reagent and a single electron transfer reagent in the one-pot synthesis of terminal olefins

Supplementary files

Article information

Article type
Communication
Submitted
24 Jul 2013
Accepted
25 Sep 2013
First published
26 Sep 2013

Chem. Commun., 2013,49, 10635-10637

Dual role of allylsamarium bromide as a Grignard reagent and a single electron transfer reagent in the one-pot synthesis of terminal olefins

Y. Li, Y. Hu and S. Zhang, Chem. Commun., 2013, 49, 10635 DOI: 10.1039/C3CC45611K

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