Issue 80, 2013

Unprecedented ortho-acylation of azoxybenzenes with α-oxocarboxylic acids by Pd-catalyzed C–H activation and decarboxylation

Abstract

A palladium-catalyzed ortho-acylation reaction of azoxybenzenes with α-oxocarboxylic acids was developed in the presence of K2S2O8. The established methodology provides a direct approach to obtain acylated azoxybenzenes in good yields.

Graphical abstract: Unprecedented ortho-acylation of azoxybenzenes with α-oxocarboxylic acids by Pd-catalyzed C–H activation and decarboxylation

Supplementary files

Article information

Article type
Communication
Submitted
19 Jul 2013
Accepted
05 Aug 2013
First published
08 Aug 2013

Chem. Commun., 2013,49, 9170-9172

Unprecedented ortho-acylation of azoxybenzenes with α-oxocarboxylic acids by Pd-catalyzed C–H activation and decarboxylation

H. Li, P. Li, Q. Zhao and L. Wang, Chem. Commun., 2013, 49, 9170 DOI: 10.1039/C3CC45492D

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