Issue 74, 2013

Vanadium-catalyzed deoxydehydration of glycols

Abstract

A survey of several metavandate (VO3) and chelated dioxovanadium derivatives shows that tetrabutylammonium dioxovanadium(V)dipicolinate most effectively catalyzes the deoxydehydration (DODH) of glycols to olefins in moderate to excellent yields with triphenylphosphine or sodium sulfite as reductants.

Graphical abstract: Vanadium-catalyzed deoxydehydration of glycols

Supplementary files

Article information

Article type
Communication
Submitted
22 Jun 2013
Accepted
23 Jul 2013
First published
25 Jul 2013

Chem. Commun., 2013,49, 8199-8201

Vanadium-catalyzed deoxydehydration of glycols

G. Chapman and K. M. Nicholas, Chem. Commun., 2013, 49, 8199 DOI: 10.1039/C3CC44656E

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