Heterometallic clusters with a new {Re3Mo3S8} core: direct synthesis, properties and DFT calculations

Yakov M. Gayfulin; Nikolay G. Naumov; Maxim R. Rizhikov; Anton I. Smolentsev; Vladimir A. Nadolinny; Yuri V. Mironov

doi:10.1039/C3CC44643C

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Heterometallic clusters with a new {Re₃Mo₃S₈} core: direct synthesis, properties and DFT calculations†

Yakov M. Gayfulin,^a Nikolay G. Naumov,*^a Maxim R. Rizhikov,^a Anton I. Smolentsev,^a Vladimir A. Nadolinny^a and Yuri V. Mironov^a

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* Corresponding authors

^a Nikolaev Institute of Inorganic Chemistry, 3, Acad. Lavrentiev Ave., Novosibirsk, Russia
E-mail: naumov@niic.nsc.ru
Fax: +7 383 330-94-89
Tel: +7 383 330-94-90

Abstract

We report the direct facile high-temperature synthesis and investigation of heterometallic rhenium–molybdenum cluster K₆[Re₃Mo₃S₈(CN)₄(CN)_2/2] (1) with a new {Re₃Mo₃S₈} core. Dissolution of polymeric compound 1 resulted in subsequent oxidation and formation of stable 23e paramagnetic anionic cluster complex [Re₃Mo₃S₈(CN)₆]⁶⁻.

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Article information

DOI: https://doi.org/10.1039/C3CC44643C
Article type: Communication
Submitted: 20 Jun 2013
Accepted: 28 Aug 2013
First published: 03 Sep 2013

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Chem. Commun., 2013,49, 10019-10021

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Heterometallic clusters with a new {Re₃Mo₃S₈} core: direct synthesis, properties and DFT calculations

Y. M. Gayfulin, N. G. Naumov, M. R. Rizhikov, A. I. Smolentsev, V. A. Nadolinny and Y. V. Mironov, Chem. Commun., 2013, 49, 10019 DOI: 10.1039/C3CC44643C

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