Issue 80, 2013

Rhodium-catalyzed intermolecular C–H amination of simple hydrocarbons using the shelf-stable nonafluorobutanesulfonyl azide

Abstract

A new procedure has been developed for the direct intermolecular C–H amination of simple hydrocarbons using shelf-stable nonafluorobutanesulfonyl azide in the presence of a dirhodium(II) tetracarboxylate catalyst under mild reaction conditions. Some mechanistic details are briefly discussed on the basis of control experiments.

Graphical abstract: Rhodium-catalyzed intermolecular C–H amination of simple hydrocarbons using the shelf-stable nonafluorobutanesulfonyl azide

Supplementary files

Article information

Article type
Communication
Submitted
19 Jun 2013
Accepted
11 Aug 2013
First published
13 Aug 2013
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2013,49, 9194-9196

Rhodium-catalyzed intermolecular C–H amination of simple hydrocarbons using the shelf-stable nonafluorobutanesulfonyl azide

J. R. Suárez and J. L. Chiara, Chem. Commun., 2013, 49, 9194 DOI: 10.1039/C3CC44594A

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