Issue 72, 2013
From the journal:

Chemical Communications

Synthesis of mono-fluorinated functionalized cyclopropanes and aziridines using the α-fluorovinyl diphenyl sulfonium salt†

Kensuke Hirotaki,a   Yui Takehiro,a   Ryo Kamaishi,a   Yasunori Yamadaa  and  Takeshi Hanamoto*a  

* Corresponding authors

a Department of Chemistry and Applied Chemistry, Saga University, Honjyo-machi 1, Saga 840-8502, Japan
E-mail: hanamoto@cc.saga-u.ac.jp
Fax: +81-952-28-8548
Tel: +81-952-28-8704

Abstract

The α-fluorovinyl diphenyl sulfonium salt 1 is attractive due to its high potential for the synthesis of mono-fluorinated cyclopropanes and aziridines as useful three-membered rings. The synthetically useful salt 1 is readily prepared from α-fluorovinyl phenyl sulfide and diphenyl iodonium salt in one step.

Graphical abstract: Synthesis of mono-fluorinated functionalized cyclopropanes and aziridines using the α-fluorovinyl diphenyl sulfonium salt

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Article information

DOI
https://doi.org/10.1039/C3CC44519D
Article type
Communication
Submitted
17 Jun 2013
Accepted
15 Jul 2013
First published
31 Jul 2013

Chem. Commun., 2013,49, 7965-7967

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Synthesis of mono-fluorinated functionalized cyclopropanes and aziridines using the α-fluorovinyl diphenyl sulfonium salt

K. Hirotaki, Y. Takehiro, R. Kamaishi, Y. Yamada and T. Hanamoto, Chem. Commun., 2013, 49, 7965 DOI: 10.1039/C3CC44519D

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